After a number of nineteenth-century scientific investigations, Russian chemist Dmitri Mendeleev discovered this principle in 1871. Many of the physical and chemical properties of lithium, such as its vigorous reactivity with water, recur in sodium, potassium, and cesium after arranging elements in increasing atomic numbers. The Periodic Law asserts that when chemical elements are enumerated in increasing atomic number order, many of their properties undergo cyclical changes, with comparable elements reoccurring at regular intervals. According to this criterion, pyridine is more aromatic than furan, but it is difficult to say by how much. As a result, the degree of aromaticity is measured in terms of reactivity by the relative tendency toward substitution rather than addition. The Arabic numbering system is the most widely accepted today.The extra stability, in turn, determines the compound’s tendency to react by substitution of hydrogen-that is, replacement of a singly bonded hydrogen atom with another singly bonded atom or group-rather than the addition of one or more atoms to the molecule via the breaking of a double bond (see substitution reaction addition reaction). Many periodic tables include both Roman and Arabic numbers. The modern IUPAC system uses Arabic numbers 1-18, simply numbering the columns of the periodic table from left to right.The CAS system used letters to differentiate main group (A) and transition (B) elements.The older IUPAC system used Roman numerals together with letters to distinguish between the left (A) and right (B) side of the periodic table.Three systems have been used to number families and groups: Recognizing Families on the Periodic TableĬolumns of the periodic table typically mark groups or families. Noble Gases: - Group 18 (VIIIA) - 8 valence electrons.Halogens: - Group 17 (VIIA) - 7 valence electrons.Oxygen Group or Chalcogens: - Group 16 (VIA) - 6 valence electrons.Nitrogen Group or Pnictogens: - Group 15 (VA) - 5 valence electrons.Carbon Group or Tetrels: - Group 14 (IVA) - 4 valence electrons.Boron Group or Earth Metals: Group 13 (IIIA) - 3 valence electrons.Transition Metals: Groups 3-12 - d and f block metals have 2 valence electrons. Alkaline Earth Metals: Group 2 (IIA) - 2 valence electrons.Alkali Metals: Group 1 (IA) - 1 valence electron.Many chemists and chemistry textbooks recognize five main families:Īnother common method of categorization recognizes nine element families: However, there are different ways of categorizing elements into families. Because element properties are largely determined by the behavior of valence electrons, families and groups may be the same. Element groups, on the other hand, are collections of elements categorized according to similar properties. The characteristics of the elements in these families are determined primarily by the number of electrons in the outer energy shell. Elements are classified into families because the three main categories of elements (metals, nonmetals, and semimetals) are very broad. Element families are indicated by numbers located at the top of the periodic table.Īn element family is a set of elements sharing common properties.
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Los Angeles County Storm Drain Network - The Los Angeles County Storm Drain System shows drains, channels, catch basins, and debris basins in the County of Los Angeles using a web-based map viewer. The Guide also provides Record of Survey Check Sheet, GPS Record of Survey Guidelines and Sample Corner Records and Records of Survey. Los Angeles County DPW " Guide to the Preparation of Records of Survey and Corner Records" - describes purposes and requirements for a Corner Record and Record of Survey, responsibilities of the private surveyor/engineer, responsibilities of the county surveyor when reviewing a Record of Survey and Corner Record. The flood insurance and building permit requirements depend on the designated flooding risk at a property. These Special Flood Hazard Areas (SFHAs) or Flood Zones include different types and levels of flooding risks. The Federal Emergency Management Agency (FEMA) publishes Flood Insurance Rate Maps (FIRMs) depicting areas subject to flood hazards. Some of the data is available for download.įlood Zone Determination Website - The Flood Zone Determination Website allows you to locate property and determine its location within a Federal flood zone. Los Angeles County GIS Data Portal – shows Administrative Boundaries, Political Boundaries, Planning and Zoning, Hazards, Demographics, Parcels, Elevation Data, LA County Base Map, LA County Streets, LA County Aerial, LA County Terrain, etc. The bench data provided is derived from the latest adjustments to date. Each quad's content includes index maps, county maps, abbreviation listings, etc. For identification purposes each quad was given a name, for example, "Rosemead", "La Mirada", "Santa Fe", etc. To facilitate the adjustment, indexing and distribution of adjusted values to the network, the county territory was divided into 33 areas or "quads". You can view property information, including parcel maps, and estimate supplemental taxes.Los Angeles County DPW Survey Division's Bench Mark Retrieval System - The Department of Public Works level net is composed of more than 1,700 miles (2,720 kilometers) of level circuits supporting in excess of 9,000 bench marks. This search tool is maintained by an independent data service. A Land Use Code Reference Guide is available to be viewed by the public. Land use code data may not be reliable for any other purpose and may not reflect pending changes or any changes to the use of property not yet reported to the Assessor’s Office. Assessor land use codes describe the actual or proposed use of property as determined by the Assessor’s Office specifically for assessment purposes. Zoning is assigned to property by the planning department of the jurisdiction where the property is located and describes the approved use of property in accordance with existing land use ordinances and regulations. The term ‘land use code’ is different from zoning. Changes to assessed value that result in roll corrections will not be reflected on the Parcel Viewer Application after September 15th. Note: The assessed value s on Parcel Viewer are updated in early July and mid-September. Accessory Dwelling Unit Disclaimer ExplanationĬAD files may be emailed along with the recorded map's date and page. .Accessibility and System Recommendations.Assessor Parcel Maps along with assessment and property related data can be accessed through Assessor Parcel Viewer. With these promises in 2024 and create some new interesting content for you Support you have given me these last four years, and I hope I can follow through Shelved for a little bit as I wait out my life's turmoil. Moment, in addition to having a busy work schedule, so these ideas may get I am doing my best to get these ideas upĪnd going, but please remember I am doing a lot of self-improvement at the I want more polarization between my Deviant Art and myīlogger so that followers for both can receive some exclusive and uniqueĬontent and only find one platform. Use this series to explore different humiliation techniques and flesh outĪmelia and Mr. X has made an appearance in this year's 30_DOC collections, and I hope to Still, we do know he enjoys forcefully feminizing young men. Reoccurring villain in my caption stories, and the mysterious Mr. Sissy roulette series, Pathway to Progress or Camp Sissywalka (I haven’tĭetermined a name) will follow varying characters as they are slowly forced toįeminize, put into compromising situations, and have their masculinity slowlyīroken at this mysterious camp. Pathway to Progress or Camp Sissywalka: To complement my (Forgotten Suitcase - A Little Tanning and Thanksgiving Dinner With A Friend – Think of them as more fleshed-out versions ofĬaptions, which can pull inspiration from existing captions or new storylines They’re essentially a two-page story circulating sissy, transformation, forcedįeminization, or body swapping. Longer stories: These are under the #sissy_stories tag, and Understanding regarding posting NSFW content, it will remain in the vault. Regarding how I can post NSFW content on DA, so until I have a firm NSFW/Mature content: I do pride myself on running clean SFWĬaptions, but I do have some NSFW content in the vault. Out cleaner there, but I have not reached a definite conclusion. To get free from this blackmailing app! I do want to do longer story captionsįor this series, so I may leave those to Blogger since the story format turns More of this caption series following Samuel and Oliver through their attempt I have decided to move forward with creating While I have sprinkled some of theģ0_DOC with Sissy-Roulette captions over the last year, the reception regarding Posted on DA, but because of my phases of inspiration, I never got too far intoĬreating a lot of captions for this series. Sissy-Roulette captions: Sissy-Roulette was a series idea I Below are the series and/orĬontent that will be exclusive for each site: Their terms of service and their advantages. Both sites will have exclusive content linked directly to Which is why I’ll be spending the next few months coming up with differentĬontent for both. Quickly ditched the idea because of how difficult it was overall to maintain, Polishing up the duller edges of both my blog and DA and creating new contentįor both, which is exclusive to both. Vary vastly sometimes from my weekly posts). Moving forward in 2024 is going to be a self-improvement yearįor me with many changes, and before you think I’m leaving, don’t worry I haveĪbout a year of captions in the vault. Know I have such a strong community that will support me regardless of what myĬaptions take on. While my topics have, and will always, vary, it is great to I surely couldn’t have done it without the support of those who follow me, I never thought I would be where I am today, and So having an opportunity, challenge, and outlet to produce such wonderfulĬontent is truly appreciated. This community for well over a decade, and I’ve been writing for just as long, Has given me the support to continue honing my writing skills. I have enjoyed creating caption stories for such a wonderful community, which Thank you all for your support these last three-plus years. Authorized players can download fashion Spin Tires directly with our customers, not registered users from a file-sharing resource in free mode. After selecting one or multiple mods download available in two ways. Also the possibility of choice of cars by make ( Nissan, VAZ, Infiniti and so on).Įvery mod Spin Tires has detailed graphical and textual description, including an overview appearance and technical peculiarities of transport. These include sections with trucks, special vehicles, SUVs, cars and even military machines. They are downloaded for free from our project and are installed for 1-2 minutes.įor players convenience, foreign and Russian machines for Spin Tires are divided into several categories. Separate attention are the vehicles of Russian production - KrAZ, Ural, KAMAZ. You can also see other fashion from the category Trucks for Spintires or go to the main section Spintires games. The variety of mods includes a powerful trucks and cars of foreign manufacture - HUMMER, AUDI, BMW. Info about the mod: A great addition added to the game Spintires MudRunner is Volvo FMX 2014 Dump Truck for v26.10.17 game version, which can be downloaded for free and without registration. Download a map of the 'Old Telegraph Track' for Spintires, you can click on the links below on the page. Players can freely and free download of fashion with our customers. This section presents the machine to Spin Tires, not in the basic game configuration. Stay engaged as developers release regular updates, bringing new challenges, levels, and features. While there may be optional purchases, the core experience is accessible to everyone, making it easy for players to dive into the urban running adventure without breaking the bank. This model means you can download and start playing without spending a dime. FREE GAMEĮnjoy the thrill without any upfront cost. The friendly competition adds a social aspect, encouraging you to outdo your pals and prove who’s the top runner in your circle. See who can run the farthest and collect the most coins. COMPETE FRIENDSĬhallenge your friends by connecting with them and competing for high scores. The changing scenery adds variety to the gameplay, keeping things fresh and engaging as you navigate through the city’s various districts. From busy streets to urban parks, each level presents a new backdrop for your running adventure. CITYSCAPESĮxplore diverse cityscapes as you run through different environments. Grab them when you can to experience moments of enhanced abilities and surges in your coin collection. Whether it’s a speed boost, invincibility, or a coin magnet, these power-ups add an extra layer of excitement to your run. POWER-UP BOOSTĭiscover special power-ups scattered throughout your adventure that can give your character a temporary advantage. It’s easy to pick up and play for a quick and entertaining gaming experience. The simplicity of the controls allows you to focus on the thrill of the run without being bogged down by complicated maneuvers. With user-friendly controls, this game is accessible to players of all skill levels. The simple yet engaging visuals create an immersive environment, making your running escapade through the city even more enjoyable. The vibrant and colorful graphics bring the urban setting to life. Whether it’s unlocking new outfits or gaining special powers, leveling up adds an exciting element of progression. LEVEL UPĪs you progress, you’ll have the opportunity to level up and enhance your character’s abilities. Quick thinking and strategic moves are key to avoiding collisions and keeping the run going. From barriers and barricades to pesky guards, you’ll need to master the art of dodging. The city is full of obstacles that stand between you and victory. Keep your eyes peeled for these valuable coins as you run, jump, and slide through the challenging course. These shiny treasures not only add to your score but also help you unlock new items and power-ups. Your mission is to collect coins scattered across the levels. It’s all about quick reflexes and navigating the city streets with agility. The fast-paced running action keeps you on your toes, dodging obstacles and racing against time. You can expect a speedy adventure as your character dashes through various urban landscapes. Put on your running shoes, princess – it’s time to dash through the subway chaos and show everyone that you’re the ultimate street-smart runner! FAST RUN Looking back, it seems like there were a LOT of projects back then, so there is a lot of just plain, ol’ junk to get out of the way. Somehow, going fishing took a back burner position to other priorities and the boat became the location to stack scrap lumber and other materials left over from various projects around the house. We bought it back in the late 1990’s primarily for fishing in the back bays around Corpus Christi and Port Aransas, with the very occasional trip into fresh water. I have some ideas that may be a little off the wall (I prefer “out of the box”) about how to proceed with parts of my build, so I will welcome any and all comments, questions, encouragement or criticism that will help me in getting a better boat out of the process. You could feel the metal flake in the gelcoat before I started and after a few compounds (still more to go), restorer, and polish it looks. Today I began compounding the old oxidation off the horizontal surfaces. Been a very good boat and Im rewarding it by restoring a number of items. Plans at the moment include using vinyl decking boards, instead of wood, for trailer bunks using HydroTurf mats, instead of carpet, for all of my horizontal deck surfaces and trying out one of Water Snake brand trolling motors from Australia. I have a 1982 Monark McFast V-172 that I bought in 1985. Fair warning – I am completely new to this boat remodeling craft so I will unashamedly beg, borrow and definitely steal ideas and techniques from here to use in my own build. I’ve been feeding my TinBoat addiction with almost daily injections of cruising the threads, getting ideas and inspiration from the builds found here to apply to my own soon-to-be dream boat/fishing machine. I’ve been hovering and lurking here, with the occasional posted comment since last summer, when I stumbled across a couple of YouTube postings with links to TinBoats. This is the only forum I’ve ever joined or even been interested in joining. Right off the bat, here, before anything else – Thanks to Jim for creating a fantastic site for ordinary fishermen and boaters to share knowledge and experiences in an enjoyable, supportive environment. The boat has been sitting beneath an RV carport for at least 8 years. What we have here is a long neglected 1982 model 1652 MonArk with a 25 horse motor by Evinrude, also 1982 model. I guess it’s finally time for me to step up to the plate. You can use this image in your creations to produce beautiful artwork. Download 3,100+ Royalty Free Instagram Logo Black and White Vector Images. Scroll down to view additional Icons, PNG-related content. The best selection of Royalty Free Instagram Logo Black and White Vector Art, Graphics and Stock Illustrations. On PNG Arts, search for related vector, realistic, and clipart images of people. 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He watched the old Annex clock with an anxious heart, as it slowly registered the flow of the river of time into the ocean of eternity.Īt 11:30 p.m., the attending guards filed into the Death Cage accompanied by the prison barber. He had hopes that the governor would, at the last moment, commute his death sentence to one of life imprisonment. He had maintained all along that something would intervene to save him from the chair. He ate sparingly of his supper and refused to take stimulants of any kind (whisky). He flatly refused all spiritual consolation and would tolerate the presence of neither preacher nor priest. Schiller grew extremely nervous when he heard the officers testing the chair, and spent the evening pacing restlessly back and forth in the death cage. Schiller, serial number 34,925, the Youngstown wife-murderer, just after midnight on June 17, 1904.Įlectrician Marden had tested the chair several times that evening and pronounced it in perfect order. NEVER BEFORE IN the gruesome history of the Annex (the official term used then for Ohio’s death row) was witnessed such a horrible and sickening sight as that which attended the execution of Michael G. I’m tired of you acting you like did all your homework when you just grabbed it from this blog. Notice to content creators (podcasters, YouTubers, bloggers, listicle regurgitators,) do not use this material without accurate accreditation to HCD. (All words and sentences in parenthesis below are the editor’s.) The prior twelve electrocutions had gone well, and there was no reason for prison officials to think Schiller’s would be any different. Schiller was executed on June 17, 1904, he was the thirteenth man to be electrocuted by the state of Ohio. Fogle’s story retold below is augmented by newspaper reports written by journalists present for the execution as official witness for the public. Īs an insider privy to all that occurred within prison walls, Fogle’s book contains exclusive information of Schiller’s execution. The first and last detailed account of his execution (until now) appeared in the 1908 book, Palace of Death, A True Tale of 59 Executed Murders, by Captain of the Guards Humphrey M. When it came to the electric chair, besides being burned or set afire, it was occasionally necessary for officials to order two, three, four, five, and even six applications of the electrical charge before they were declared dead.īut that’s not what happened to Ohio State Penitentiary prisoner Michael Schiller during the midnight hour of June 17, 1904. In all the case studies of botched executions throughout the world, there have been: prisoners whose neck had to be hacked several times before it was separated prisoners hanged who were partially or fully decapitated those who strangled to death without a broken neck and a few who even survived their own hanging. Schiller’s story is unique because he is the only executed prisoner who came back to life. His absence from history of executed criminals is just as baffling to me as his own executions. Schiller does not appear on any “Top 10” listicle, nor in Wikipedia, or even on the Death Penalty Information Center’s 10,000-page website – the largest resource for the dissemination of death penalty related information. Content churners are untrained, poorly paid, and the yet-to-be observed consequence is that the world is drowning in content. Ad revenue is the motive and there’s no motive to reward quality work because that’s just how the USA is now. Over the last twenty-years, I have become convinced that the internet is 10-percent original, and the rest is just a copy.Ĭase in point: When it comes to botched executions, the ‘same’ listicle gets republished several times a year by different content farms looking for cheap and easy traffic to make a fast buck. 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Videoder Apk comes with a free download of unlimited videos and music. In June, People revealed the identity of the white bird living with Zeta in the teaser trailer, as Debbie, voiced by Tiffany Haddish, one of several voice actors who were not listed in the initial casting.The conception of the original project was also odd, though perhaps no odder than that of most of other big-budget animated pictures aimed at families. Among several new characters confirmed to appear in the movie was Silver, a bird first introduced in the Angry Birds 2 game. When the film's first full trailer was released on March 27, 2019, more details about the sequel's characters and their voice roles were revealed. Jones will voice a new female villain, revealed to be Zeta in the teaser trailer. In December 2018, Nicki Minaj joined the cast of the film. Upon its release, the teaser trailer briefly revealed that Hal, a green boomerang bird from the first film, will return in the sequel. Anthony Padilla would return to voice Hal. The following day, producer John Cohen announced in a tweet that Awkwafina will voice Courtney, the first named female pig in the Angry Birds franchise that briefly appeared in the teaser. Sudeikis, Gad, McBride, Hader, Rudolphand Dinklage will reprise their roles from the first film. In April 2018, the majority of the voice cast was announced. While he was not in a position to offer further details about the plot and characters, which remained highly unknown until the months before the film's release, he expressed hope that it would be a better film than the first installment. In the summer of 2017, production designer Pete Oswald stated that the sequel would be more of an adventure movie that introduces new characters and locations into the world established in The Angry Birds Movie. John Cohen will return from The Angry Birds Movie to serve as producer, with animation again handled by Sony Pictures Imageworks. Imageworks' sister studio Sony Pictures Animation will release the film under their banner, despite having dropped out of co-producing the project beforehand and had not co-produced the first film either. On July 25, 2019, American singer-songwriter Kesha released her song "Best Day" for the film as a single. Days later, Luke Combs released a song, "Let's Just Be Friends" for the film as a single as well. Both singles were played in the film's end credits.Ī sequel to The Angry Birds Movie was announced in August 2016. It will be directed by The Marvelous Misadventures of Flapjack creator Thurop Van Orman, co-directed by John Rice, and written by Peter Ackerman. Heitor Pereira, who composed in the first film, returns to compose the score of The Angry Birds Movie 2. Sean Charmatz as Invisible Pig / Teacher. Sunday Rose Kidman-Urban as Lily / Isla.Faith Margaret Kidman-Urban as Beatrice / Sophie.King Mudbeard, ruler of the Bad Piggies, plots revenge against the Angry Birds after they devastated his homeland in a prior battle to reclaim their eggs, leading to a comical war that seemingly does not end until a mysterious purple bird named Zeta, threatens them all with her own plans to usher in a new ice age with cryokinetic technology after being fed up with living in a remote, arctic island. To avoid a frozen fate, the Birds and Pigs may have to make the impossible choice to forge an uneasy alliance against Zeta and embark on a new adventure. |
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